2-Chloro-N-methyl-N-phenylacetamide
نویسندگان
چکیده
In the title compound, C(9)H(10)ClNO, the non-H atoms, excluding the phenyl group, are almost coplanar (r.m.s. deviation of the non-H atoms = 0.1015 Å). The dihedral angle formed between this plane and the benzene ring is 87.07 (5)°. Weak inter-molecular C-H⋯O inter-actions help to stabilize the packing.
منابع مشابه
2-Chloro-N-isopropyl-N-phenylacetamide
In the title compound, C(11)H(14)ClNO, the herbicide propachlor, there are significant differences between the three N-C bond lengths [N-C(carbon-yl) = 1.354 (3) Å, N-C(phen-yl) = 1.444 (2) Å and N-C(isoprop-yl) = 1.496 (3) Å], indicating the presence of π delocalization involving the carbonyl group. The N atom lies 0.074 (2) Å from the plane defined by the the three bonded C atoms.
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In the title compound, C(8)H(8)ClNO, the conformations of the N-H and C=O bonds are anti to each other, but the C-Cl and C=O bonds in the side chain are syn. The mol-ecules are linked by N-H⋯O hydrogen bonds into infinite chains running in the [101] direction.
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The conformation of the N-H bond in the structure of the title compound, C(10)H(12)ClNO, is syn to the ortho methyl group, similar to that observed with respect to the meta methyl group in 2-chloro-N-(3-methyl-phen-yl)acetamide and the ortho-chloro group in 2-chloro-N-(2-chloro-phen-yl)acetamide. The geometric parameters are similar to those of other acetanilides. The mol-ecules are linked into...
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